Phosphine–Stibine and Phosphine–Stiborane peri-Substituted Donor–Acceptor Complexes
نویسندگان
چکیده
Two novel Sb(III) and Sb(V) peri-substituted acenaphthene phosphorus−antimony compounds were prepared. The compound, 1, was prepared via reacting the organolithium precursor with dichloro(p-tolyl)Stibine, 2 by chlorination of 1. Both 1 characterized multinuclear (1H, 13C 31P) NMR spectroscopy, their molecular structures resolved single-crystal X-ray diffraction. show a dative P−Sb interaction antimony being acceptor group in both cases owing to its Lewis acidity.
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ژورنال
عنوان ژورنال: Molbank
سال: 2023
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1653